Zhang, Ming-Lu published the artcileSwitchable, Reagent-Controlled C(sp3)-H Selective Iodination and Acetoxylation of 8-Methylquinolines, Computed Properties of 209919-30-2, the publication is Journal of Organic Chemistry (2022), 87(9), 5730-5743, database is CAplus and MEDLINE.
An efficient Pd-catalyzed C(sp3)-H selective iodination of 8-methylquinolines I (R = H, Ph, 4-chlorophenyl; R1 = H, Cl, Ph, etc.; R2 = H, F, Cl, Br; R3 = H, Cl, Br, I) is reported herein for the first time. Because of the versatility of organic iodides, the method offers a facile access to various C8-substituted quinolines II. By slightly switching the reaction conditions, an efficient C(sp3)-H acetoxylation of 8-methylquinolines I has also been enabled. Both approaches feature mild reaction conditions, good tolerance of functional groups, and a broad substrate scope.
Journal of Organic Chemistry published new progress about 209919-30-2. 209919-30-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids,Boronic acid and ester, name is 4-Chloro-2-methylphenylboronic acid, and the molecular formula is C7H6N2O2S, Computed Properties of 209919-30-2.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics