Li, Yan-Kai published the artcileThe magic of integration: Exploring the construction of dithienylethene-based infinite coordination polymers and their synergistic effect for gaseous ammonia probe applications, Synthetic Route of 219537-97-0, the publication is Chinese Chemical Letters (2016), 27(4), 518-522, database is CAplus.
Infinite coordination polymers are recognized as excellent platform for functionalization. Dithienylethene motifs, which are one of the most attractive functional moieties, were incorporated into an infinite coordination polymer, to deliver a smart porous material that can response to external stimuli. The obtained dithienylethene-based infinite coordination polymers (named Cu-DTEDBA) share the advantages of both infinite coordination polymers (porosity and stability) and dithienylethene motifs (photochromism). The phys. and chem. properties of Cu-DTEDBA were characterized by FTIR, TEM, SEM, XRD, TGA, UV-visible, EDX and BET. Also, the combination of dithienylethene and infinite coordination polymers gives rise to a synergistic effect, which induces functional behaviors of ammonia sensor applications. Both open and closed forms of Cu-DTEDBA exhibit distinct colorimetric change upon exposure to gaseous ammonia, which is not observed in dithienylethene free mols.
Chinese Chemical Letters published new progress about 219537-97-0. 219537-97-0 belongs to chlorides-buliding-blocks, auxiliary class Fused/Partially Saturated Cycles,Cyclopentenes, name is 5-Chloro-3-[2-(5-chloro-2-methylthien-3-yl)cyclopent-1-en-1-yl]-2-methylthiophene, and the molecular formula is C15H14Cl2S2, Synthetic Route of 219537-97-0.
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