Chen, Kuang-Yen published the artcileTetrapodal Molecular Switches and Motors: Synthesis and Photochemistry, Application In Synthesis of 219537-97-0, the publication is Journal of Organic Chemistry (2014), 79(15), 7032-7040, database is CAplus and MEDLINE.
The design, synthesis, and dynamic behavior of a series of novel tetrapodal mol. switches and motors containing common functional groups for attachment to various inorganic and organic surfaces are presented. Using a Diels-Alder reaction, an anthracene unit with four functionalized alkyl substituents (“legs”) was coupled to maleimide-functionalized mol. switches or motors under ambient conditions. Terminal functional groups at the “legs” include thioacetates and azides, making these switches and motors ideal candidates for attachment to metallic or alkyne-functionalized surfaces. UV/vis absorption spectroscopy shows that the mol. switches and motors retain their ability to undergo reversible photoinduced and/or thermally induced structural changes after attachment to the tetrapodal anthracene.
Journal of Organic Chemistry published new progress about 219537-97-0. 219537-97-0 belongs to chlorides-buliding-blocks, auxiliary class Fused/Partially Saturated Cycles,Cyclopentenes, name is 5-Chloro-3-[2-(5-chloro-2-methylthien-3-yl)cyclopent-1-en-1-yl]-2-methylthiophene, and the molecular formula is C15H14Cl2S2, Application In Synthesis of 219537-97-0.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
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