Dong, Bin published the artcileCation Modules as Building Blocks Forming Supramolecular Assemblies with Planar Receptor-Anion Complexes, Application In Synthesis of 23616-79-7, the publication is Journal of the American Chemical Society (2013), 135(4), 1284-1287, database is CAplus and MEDLINE.
Ion-based materials were fabricated through ion pairing of planar receptor-anion complexes and cation modules as neg. and pos. charged building blocks, resp. Anion receptors that could not form soft materials by themselves provided mesophases upon anion binding and subsequent ion pairing with aliphatic cation modules. The mesogenic behaviors were affected by structural modification of both the cation module and the anion receptor. Synchrotron x-ray diffraction measurements suggested the formation of columnar mesophases with contributions from charge-by-charge and charge-segregated arrangements. Flash-photolysis time-resolved microwave conductivity measurements further revealed a higher charge-carrier mobility in the assembly with a large contribution from the charge-segregated arrangement than in the charge-by-charge-based assembly.
Journal of the American Chemical Society published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Application In Synthesis of 23616-79-7.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics