Yao, Yan’s team published research in Synlett in 31 | CAS: 939-99-1

Synlett published new progress about 939-99-1. 939-99-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Benzyl chloride,Benzene, name is 1-(Chloromethyl)-4-(trifluoromethyl)benzene, and the molecular formula is C7H16ClNO2, Formula: C8H6ClF3.

Yao, Yan published the artcileElectrochemical Synthesis of Quinazolinones by the Metal-Free and Acceptor-Free Dehydrogenation of 2-Aminobenzamides, Formula: C8H6ClF3, the publication is Synlett (2020), 31(18), 1795-1799, database is CAplus.

An efficient approach has been developed for the construction of quinazolin-4(3H)-ones by the selective anodic dehydrogenative oxidation/cyclization of benzylic chlorides and 2-aminobenzamides [e.g., 2-aminobenzamide + benzyl chloride → 2-phenylquinazolin-4(3H)-one I (80%) employing RVC as anode, Pt as cathode, Bu4NBF4 as electrolyte and MeCN as solvent in undivided cell at constant current of 10mA at 80°]. The method features acceptor-free and metal-free dehydrogenation of amines to imines; a subsequent intermol. addition provides the products in moderate to good yields.

Synlett published new progress about 939-99-1. 939-99-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Benzyl chloride,Benzene, name is 1-(Chloromethyl)-4-(trifluoromethyl)benzene, and the molecular formula is C7H16ClNO2, Formula: C8H6ClF3.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics