Xiao, Jing published the artcilePhosphonic acid mediated practical dehalogenation and benzylation with benzyl halides, Related Products of chlorides-buliding-blocks, the publication is RSC Advances (2019), 9(39), 22343-22347, database is CAplus and MEDLINE.
For the first time, by using H3PO3/I2 system, various benzyl chlorides and bromides RCH2X (R = C6H5, 4-O2NC6H4, 1-naphthyl, etc.; X = Cl, Br) were dehalogenated successfully. In the presence of H3PO3, benzyl halides underwent electrophilic substitution reactions with electron-rich arenes, leading to a broad range of diarylmethanes RCH2R1 (R1 = C6H5, 2,4,6-(CH3)3C6H2, 4-CH3OC6H4, etc.) in good yields. These transformations feature green, cheap reducing reagents and metal-free conditions.
RSC Advances published new progress about 939-99-1. 939-99-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Benzyl chloride,Benzene, name is 1-(Chloromethyl)-4-(trifluoromethyl)benzene, and the molecular formula is C14H26O2, Related Products of chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics