Luan, Pengqian published the artcileAqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C-C formation and enzymatic C=C asymmetric hydrogenation, Recommanded Product: 4-Chloro-2-methylphenylboronic acid, the publication is Green Chemistry (2021), 23(5), 1960-1964, database is CAplus.
An aqueous chemoenzymic cascade reaction combining Pd-catalyzed C-C formation and enzymic C=C asym. hydrogenation (AH) was developed for enantioselective synthesis of tertiary α-aryl cycloketones in good yields and excellent enantioselectivities. The stereopreference of the enzyme in AH of α-aryl cyclohexenones was studied. An enantiocomplementary enzyme was obtained by site-directed mutation.
Green Chemistry published new progress about 209919-30-2. 209919-30-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids,Boronic acid and ester, name is 4-Chloro-2-methylphenylboronic acid, and the molecular formula is C7H8BClO2, Recommanded Product: 4-Chloro-2-methylphenylboronic acid.
Referemce:
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Chlorides – an overview | ScienceDirect Topics