Hu, Weitao published the artcileSynthesis of Multisubstituted Allylic Alcohols via a Nickel-Catalyzed Cross-Electrophile Ring-Opening Reaction, SDS of cas: 620-20-2, the publication is Organic Letters (2022), 24(31), 5751-5755, database is CAplus and MEDLINE.
Herein, a nickel-catalyzed cross-electrophile ring-opening reaction of vinyl epoxides I (R1 = Ph, 1-naphthyl, benzodioxol-5-yl, etc.; R2 = H, Me, phenyl; R3 = H, Ph, furan-2-yl, thiophen-2-yl) was reported, wherein aryl iodides, alkyl iodides, and benzyl chlorides R4X (R4 = Pr, cyclohexyl, phenyl; X = I, Cl) can all serve as the electrophilic coupling partners, providing a new approach to preparing multisubstituted allylic alcs. R1C(CH(OH)R3)=C(R2)CH2R4. This new method features broad substrate scope multisubstituted allylic alcs., good step-economy, and high L/B- and E/Z selectivity as well as mild reaction conditions.
Organic Letters published new progress about 620-20-2. 620-20-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Benzyl chloride,Benzene, name is 3-Chlorobenzylchloride, and the molecular formula is C7H6Cl2, SDS of cas: 620-20-2.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics