Synthesis, structure, and dynamic behavior in solution of arylamino-1,3,5-triazines was written by Belyakov, P. A.;Shastin, A. V.;Strelenko, Yu. A.. And the article was included in Russian Chemical Bulletin in 2005.Computed Properties of C9H6Cl2N4 The following contents are mentioned in the article:
Ten unsym. substituted arylamino-1,3,5-triazines were synthesized and studied by dynamic NMR spectroscopy. The free energies of the hindered rotation are in 59-77 kJ mol-1 range. Using difference-mode NOE NMR experiments, the structures of the major and minor rotation isomers were proved. The DFT B3LYP/6-31G* calculations were performed. The difference between the calculated rotation barriers and the exptl. values obtained by line shape anal. is less than 7.6 kJ mol-1. The height of the rotation barrier varies in a 18 kJ mol-1 range depending on the substituents in the triazine ring. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Computed Properties of C9H6Cl2N4).
4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of C9H6Cl2N4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics