Nguyen, Tung Thanh published the artcileAminoquinoline-directed, cobalt-catalyzed carbonylation of sulfonamide sp2 C-H bonds, SDS of cas: 10543-42-7, the publication is Chemical Communications (Cambridge, United Kingdom) (2017), 53(37), 5136-5138, database is CAplus and MEDLINE.
We report a method for cobalt-catalyzed, aminoquinoline-directed sp2 C-H bond carbonylation of sulfonamides. The reactions proceed in a dichloroethane solvent, and employ diisopropyl azodicarboxylate as a carbon monoxide source, Mn(OAc)2 as a cooxidant and potassium pivalate as a base. Halogen, ester, and amide functionalities are compatible with the reaction conditions. This method allows for a short and efficient synthesis of saccharin derivatives
Chemical Communications (Cambridge, United Kingdom) published new progress about 10543-42-7. 10543-42-7 belongs to chlorides-buliding-blocks, auxiliary class Other Aromatic Heterocyclic,Chloride,Sulfonyl chlorides,Ester, name is Coumarin-6-sulfonyl chloride, and the molecular formula is C9H5ClO4S, SDS of cas: 10543-42-7.
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