Anomeric O-alkylation. Part 16. Synthesis of hetaryl glycosides and their glycosyl donor properties was written by Huchel, Ursula;Schmidt, Christoph;Schmidt, Richard R.. And the article was included in European Journal of Organic Chemistry in 1998.Recommanded Product: 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine The following contents are mentioned in the article:
Anomeric O-hetarylation of tetra-O-benzyl- and tetra-O-acetylglucose can be directly performed with electron-deficient heteroaromatic/heterocyclic systems, which contain imide halide moieties. The reactions were carried out in the presence of a base and led, through an exchange of the halide by the glucopyranosyloxy moiety. β-Products were obtained predominantly or exclusively. Systems bearing >1 imide halide moiety, such as cyanuric fluoride or 5-chloro-2,4,6-trifluoropyrimidine, can be employed for successive anomeric O-hetarylations. Investigation of the glycosyl donor properties of O-glucosyl heteroaromatic imidates with 6-O-and 4-O-unprotected glucose derivatives as acceptors and comparison of the results obtained with data for the corresponding β-trichloroacetimidates, reveals that 2,3,5,6-tetrafluoropyridin-4-yl glucopyranosides exhibit similar properties. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Recommanded Product: 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine).
4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics