Optoelectronic and charge transport properties of D-n-A type 1,3,5-triazine derivatives: A combined experimental and DFT study was written by V. M., Vidya;Pola, Someshwar;Chetti, Prabhakar. And the article was included in Spectrochimica Acta in 2021.Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine The following contents are mentioned in the article:
The synthesis of five D-n-A type star-shaped octupolar mols. is presented in the current work. The exploration of the potential applicability of mols. under study in organic optoelectronics as electron or hole transporting materials is carried out by DFT methods. All the mols. have a 1,3,5-triazine core, which acts as an electron acceptor (A). Ph ring and pyridine ring act as electron donors (D) in AZ and PZ series of mols. resp. The donor and acceptor core are connected by -NH bridge (n). The crystal structure of a mol. in the PZ series is elucidated. Thermogravimetric studies are carried out to confirm the thermal stability of mols. The frontier MOs of mols. are characterized with the help of cyclic voltammetry. With the assistance of DFT methodologies, the whole research presented in this work focuses on the electronic excitations, reorganization energies, electron affinity, ionization potential and features of frontier MOs of mols. The investigation of the variation of optoelectronic properties of mols. with changing patterns of nucleophilic substitution on 1,3,5-triazine core and presence of a hetero (nitrogen) atom in the donor part of the mol. is also accomplished. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine).
4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics