Tackling realistic Li+ flux for high-energy lithium metal batteries was written by Zhang, Shuoqing;Li, Ruhong;Hu, Nan;Deng, Tao;Weng, Suting;Wu, Zunchun;Lu, Di;Zhang, Haikuo;Zhang, Junbo;Wang, Xuefeng;Chen, Lixin;Fan, Liwu;Fan, Xiulin. And the article was included in Nature Communications in 2022.Application of 7447-41-8 The following contents are mentioned in the article:
Electrolyte engineering advances Li metal batteries (LMBs) with high Coulombic efficiency (CE) by constructing LiF-rich solid electrolyte interphase (SEI). However, the low conductivity of LiF disturbs Li+ diffusion across SEI, thus inducing Li+ transfer-driven dendritic deposition. In this work, we establish a mechanistic model to decipher how the SEI affects Li plating in high-fluorine electrolytes. The presented theory depicts a linear correlation between the capacity loss and c.d. to identify the slope k (determined by Li+ mobility of SEI components) as an indicator for describing the homogeneity of Li+ flux across SEI, while the intercept dictates the maximum CE that electrolytes can achieve. This model inspires the design of an efficient electrolyte that generates dual-halide SEI to homogenize Li+ distribution and Li deposition. The model-driven protocol offers a promising energetic anal. to evaluate the compatibility of electrolytes to Li anode, thus guiding the design of promising electrolytes for LMBs. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application of 7447-41-8
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics