Probing topology of supramolecular complexes between cyclodextrins and alkali metals by ion mobility-mass spectrometry was written by Przybylski, Cedric;Bonnet, Veronique. And the article was included in Carbohydrate Polymers in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:
In this study, the size and shape of supramol. assemblies between cyclooligosaccharides and proton, ammonium or a series of alkali metals by electrospray coupled to trapped ion mobility-mass spectrometry (ESI-TIMS) have investigated. Native cyclodextrins (CD) were selected as models, and collision cross section (CCS) values were deducted for the main pos. singly and doubly charged species. Exptl. CCS values were in good agreement with those obtained from mol. modeling. Due to the high mobility resolving power and resolution, it was possible to highlight the presence of various conformers. Also, TIMS allowed to discriminate and estimate the content of various orientations from non-covalent nanotubes-based CD, involving secondary/secondary rim hydroxyl groups (head-to head), primary/secondary rim (head-to-tail) hydroxyl groups or primary/primary rim (tail-to-tail) hydroxyl groups interactions. Such results pave the way for a better knowledge of the topol. of cyclooligosaccharides based supramol. complexes, demonstrating that TIMS can be a particularly attractive mol. descriptor. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Synthetic Route of ClLi
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics