PdPtRu nanocages with tunable compositions for boosting the methanol oxidation reaction was written by Leng, Zihan;Wu, Xingqiao;Li, Xiao;Li, Junjie;Qian, Ningkang;Ji, Liang;Yang, Deren;Zhang, Hui. And the article was included in Nanoscale Advances in 2022.COA of Formula: Cl4Na2Pd The following contents are mentioned in the article:
PtRu/C is a well-known com. electrocatalyst with promising performance for the methanol oxidation reaction (MOR). Further improving the MOR properties of PtRu-based electrocatalysts is highly desirable, especially through structure design. Here we report a facile approach for the synthesis of PdPtRu nanocages with different components through a seed-mediated approach followed by chem. etching. The Pd-PtRu nanocubes were first generated using Pd nanocubes as the seeds and some Pd atoms were subsequently etched away, leading to the nanocages. When evaluated as electrocatalysts for the MOR in acidic media, the PdPtRu nanocages exhibited substantially enhanced catalytic activity and stability relative to com. Pt/C and PtRu/C. Specifically, PdPt2.5Ru2.4 achieved the highest specific (8.2 mA cm-2) and mass (0.75 mA mgPt-1) activities for the MOR, which are 2.2 and 4.2 times higher than those of com. Pt/C. Such an enhancement can be attributed to the highly open structure of the nanocages, and the possible synergistic effect between the three components. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6COA of Formula: Cl4Na2Pd).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.COA of Formula: Cl4Na2Pd
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics