Ultrathin Fe-Nx-C single-atom catalysts with bifunctional active site for simultaneous production of ethylene and aromatic chlorides was written by Gan, Guoqiang;Li, Xinyong;Fan, Shiying;Yin, Zhifan;Wang, Liang;Chen, Guohua. And the article was included in Nano Energy in 2021.Product Details of 75-57-0 The following contents are mentioned in the article:
Ethylene evolution reaction (EER) by electrochem. dechlorination of 1,2-dichloroethane is a promising and an economical strategy. The process is however severely impeded by the poor reactivity of catalysts, the accumulation of HCl in the electrolyte as well as low value-added byproducts at anode. Herein, a bifunctional ultrathin Fe-Nx-C single-atom catalysts (SACs) has been successfully prepared and investigated as both cathode and anode material for EER and aromatic chlorination reaction (ACR), resp. The generated HCl was recycled as a chlorinating reagent. The Fe-Nx-C SACs exhibited an excellent electrocatalytic performance simultaneously for both EER and ACR with high ethylene and para-chloroanisole selectivity obtained. The first-principles calculations indicated that Fe-N4 was the dominating catalytic active site for the generation of ethylene as well as para-chloroanisole. The coupling strategy of ACR at anode not only can accelerate the reaction rate of EER, but also provide a highly-efficient and atom-economical approach for the production of valuable ethylene and aromatic chlorides. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Product Details of 75-57-0).
Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Product Details of 75-57-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics