Gold nanoparticles optical properties induced by water and an ionic liquid (bmimBF4) inside cationic reverse micelles was written by Blach, Diana;Martinez O., Fernando. And the article was included in New Journal of Chemistry in 2017.Electric Literature of C25H46ClN The following contents are mentioned in the article:
The authors report the effect of a polar solvent entrapped in benzyl-n-hexadecyldimethylammonium chloride (BHDC) reverse micelles (RMs) as nanoreactors for the synthesis of gold nanoparticles (AuNPs). We evaluate how the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborate (bmimBF4) and water inside the RMs could control the interactions at the interface as a key factor that affects the final properties of the synthesized nanoparticles. The results show that the bmimBF4 supramol. network under confinement plays an important role in the nucleation and growth mechanism of AuNPs. In addition, the results show how the polar solvent could induce a specific interaction at the interface, including ionic segregation, which affects the BHDC chloride (Cl–) counterion availability at the interface, droplet size, interface flexibility and thus the material exchange rate between droplets. These factors strongly influence the AuNPs size, polydispersity, morphol. and crystallinity. The RTIL bmimBF4 in BHDC RMs induces a decrease in ionic segregation of the Cl– ions available at the interface which favors sphericity and monocrystallinity in the AuNPs formed. Moreover, water does not affect the availability of Cl– ions at the interface, and the insertion of these ions in the previous crystalline layer is a key factor in the anisotropy and polycrystallinity of the AuNPs obtained. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Electric Literature of C25H46ClN).
N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of C25H46ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics