Volume properties of the ternary systems (LiCl + LiB5O8 + H2O) and (Li2SO4 + LiB5O8 + H2O) from 283.15 to 363.15 K and 101.325 kPa was written by Yuan, Fei;Li, Hua;Li, Long;Wang, Shiqiang;Guo, Yafei;Deng, Tianlong. And the article was included in Journal of Chemical Thermodynamics in 2022.Electric Literature of ClLi The following contents are mentioned in the article:
In this study, densities of the two ternary aqueous solution systems (LiB5O8 + LiCl + H2O) and (LiB5O8 + Li2SO4 + H2O) were measured using an accurate digital vibrating-tube densimeter from 283.15 to 363.15 K at an interval of 5 K and 101.325 kPa. B5O–8 in aqueous solution was in the form of [B5O6(OH)4]–. Therefore, the complex aqueous solution of LiB5O8 is in the form of Li[B5O6(OH)4]. Subsequently, the mean apparent molar volume (VθΦ) and mixing ion-interaction parameters (θva,a’ and ψvc,a,a’, c = Li+, a = B5O6(OH)–4, a’= Cl– or SO2-4) against temperature were obtained using the Pitzer equation for the first time. And then, the temperature-dependence equations for the Pitzer mixing ion-interaction parameters and the relevant temperature correlation coefficients of the equation aj, i.e. [f (ai, T) = a1 + a2ln(T/298.15) + a3(T – 298.15) + a4/(620 – T) + a5/(T – 227)] were also obtained through the least square fitting. These volumetric properties and parameterization Pitzer parameters obtained in this work could hopefully be used for the quant. predictive calculation of the physicochem. properties of the mixed electrolytes containing lithium, chloride, and sulfate ions at any temperature This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Electric Literature of ClLi
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics