Bakhtin, Stanislav published the artcileCatalytic activity of tertiary amines with antisymbatic change of basic and nucleophilic properties in the chloroxypropylation reaction of acetic acid, Quality Control of 23616-79-7, the publication is Reaction Kinetics, Mechanisms and Catalysis (2016), 119(1), 139-148, database is CAplus.
The kinetic dependence of the reaction of (chloromethyl)oxirane ring-opening by acetic acid in the presence of tertiary amines R3N and RnNMe3–n has been studied. The orders of reaction with respect to acid and catalyst have been determined The nucleophilicity of amines used has been measured in the quaternization reaction of R3N and RnNMe3–n by benzyl chloride (Menshutkin reaction). On the basis of correlations “amines structure-catalytic activity”, it has been shown that amines act as nucleophiles in this reaction.
Reaction Kinetics, Mechanisms and Catalysis published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Quality Control of 23616-79-7.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics