Zanella, Yannick’s team published research in Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry in | CAS: 866-23-9

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C11H22N2O4, Name: Diethyltrichloromethylphosphonate.

Zanella, Yannick published the artcileNew route to 1-formylalkylphosphonates using diethyl trichloromethylphosphonate as a precursor, Name: Diethyltrichloromethylphosphonate, the publication is Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1995), 2835-8, database is CAplus.

(EtO)2P(O)CCl3 and Me3SiCl were converted by a three-step sequence beginning with BuLi into α-phosphorylated α-silylated α-substituted carbanions, (EtO)2P(O)CRLiSiMe3 [I; R = Pr, C5H11, C7H15, C12H25, CH:CH2, crotyl, ClCH2(CH2)n, n = 2,3]. I reacts with Et formate in the presence of Me3SiCl to give transient silylated acetals, (EtO)2P(O)CR(SiMe3)CH(OEt)(OTMS), which readily undergo acid hydrolysis to afford 1-formylalkylphosphonates, (EtO)2P(O)CHRCHO, in good yield.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C11H22N2O4, Name: Diethyltrichloromethylphosphonate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics