Joung, Seewon published the artcileNi-catalyzed 1,2-benzylboration of 1,2-disubstituted unactivated alkenes, Recommanded Product: 1-(Chloromethyl)-4-(trifluoromethyl)benzene, the publication is Chemical Science (2019), 10(47), 10944-10947, database is CAplus and MEDLINE.
Nickel-catalyzed 1,2-carboboration of alkenes is emerging as a useful method for chem. synthesis. Prior studies have been limited to only the incorporation of aryl groups. In this manuscript, a method for the 1,2-benzylboration of unactivated alkenes is presented. The reaction combines readily available alkenes, diboron reagents and benzylchlorides to generate synthetically versatile products with control of stereochem. The utility of the products as well as the mechanistic details of the process are also presented.
Chemical Science published new progress about 939-99-1. 939-99-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Benzyl chloride,Benzene, name is 1-(Chloromethyl)-4-(trifluoromethyl)benzene, and the molecular formula is C8H6ClF3, Recommanded Product: 1-(Chloromethyl)-4-(trifluoromethyl)benzene.
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https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics