Simon, Cedric published the artcileMild Niobium-Catalyzed [2 + 2 + 2] Cycloaddition of Sila-triynes: Easy Access to Polysubstituted Benzosilacyclobutenes, Synthetic Route of 14799-94-1, the publication is Organic Letters (2015), 17(4), 844-847, database is CAplus and MEDLINE.
A new and efficient synthesis of highly sensitive benzosilacyclobutenes has been developed. For the first time, these compounds can be synthesized in very high yields by a mild, unprecedented intramol. niobium-catalyzed [2 + 2 + 2] cycloaddition of easily accessible tetrasubstituted sila-triynes. An easy access to highly functionalized benzosilacyclobutenes enlarging the number of potential applications in organic and material chem. is described.
Organic Letters published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C9H4F6O, Synthetic Route of 14799-94-1.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics