Tonzola, Christopher J. published the artcileNew silicon-containing polyquinolines: Synthesis, characterization, and electroluminescence, Synthetic Route of 14799-93-0, the publication is Macromolecular Chemistry and Physics (2005), 206(13), 1271-1279, database is CAplus.
This study reports the synthesis, characterization, and electroluminescent device application of three new silicon-containing polyquinolines: poly(2,2′-(bis(p-phenyl)-diphenylsilane)-6,6′-bis(4-Ph quinoline)), poly(2,2′-(bis(p-phenyl)octylmethylsilane)-6,6′-bis(4-Ph quinoline)), and poly(2,2′-(bis(p-phenyl)diphenylsilane)-6,6′-bis(4-hexylquinoline)). The polymers with alkyl side chains were soluble in organic solvents. The new polymers showed robust thermal properties with glass transitions of 161°-339°. Cyclic voltammetry of the polymers revealed quasireversible reductions with onsets of -1.55 to -1.71 V (vs SCE) and corresponding electron affinities of 2.69-2.85 eV. Organic light-emitting devices using new polyquinolines as emissive materials showed blue (CIE coordinates = 0.21, 0.20) or blue-green (0.23, 0.36) electroluminescence with a moderate brightness (≈140 cd·m-2) and efficiency (0.04%). The results demonstrate that silicon-containing polyquinolines are promising n-type wide band-gap semiconductors for organic electronics.
Macromolecular Chemistry and Physics published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C14H26O2, Synthetic Route of 14799-93-0.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics