On April 30, 2018, Sawatzky, Ryan S.; Stradiotto, Mark published an article.Recommanded Product: 452-75-5 The title of the article was (DPEPhos)Ni(mesityl)Br: An Air-Stable Pre-Catalyst for Challenging Suzuki-Miyaura Cross-Couplings Leading to Unsymmetrical Biheteroaryls. And the article contained the following:
The successful application of (DPEPhos)Ni(mesityl)Br as a pre-catalyst in the Suzuki-Miyaura cross-coupling of heteroaryl chlorides or bromides and heteroaryl boronic acids is reported. The use of (DPEPhos)Ni(mesityl)Br in this context allows for such reactions to be conducted under mild conditions (2 mol% Ni, 25 °C), including cross-couplings leading to unsym. biheteroaryls. Successful transformations of this type involving problematic pyridinyl boronic acid substrates (10 mol% Ni, 60 °C) are also described. The experimental process involved the reaction of 4-Chloro-2-fluorotoluene(cas: 452-75-5).Recommanded Product: 452-75-5
The Article related to heteroaryl halide heteroaryl boronic acid nickel suzuki miyaura, preparation unsym biheteroaryl, nickel suzuki miyaura cross coupling catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Recommanded Product: 452-75-5
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics