On September 4, 1990, Lai, J. S.; Wu, Rey F.; Lin, Ivan J. B.; Cheng, M. C.; Wang, Yu published an article.Product Details of 5034-06-0 The title of the article was Preparation of sulfur ylide complexes of platinum by phase transfer catalysis. And the article contained the following:
Various sulfur ylide complexes of Pt were prepared by the phase transfer catalysis (PTC). Thus, reaction of Pt(PR3)2Cl2 (R = Me, Ph) in CH2Cl2 with [S(O)(CH3)3]I under PTC/OH- conditions give complexes {Pt(PR3)2[(CH2)2S(O)(CH3)]}I, which contain a bidentate double sulfur ylide. With Pt(dppe)Cl2 [dppe = Ph2P(CH2)2PPh2] as starting material, a similar product was obtained. But when Pt(dppm)Cl2 [dppm = Ph2PCH2PPh2] was treated with [S(O)(CH3)3]Cl under PTC/OH- conditions, an unexpected product {Pt(PPh2CH3)(PPh2OH)[(CH2)2S(O)(CH3)]}Cl was obtained. This compound contains a bidentate double sulfur ylide and two unsym. phosphines resulting from the base hydrolysis of dppm. Compound {Pt(PPh3)2[(CH2)2S(O)(CH3)]}I, was subjected to an x-ray diffraction study. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Product Details of 5034-06-0
The Article related to phase transfer catalyzed sulfur ylide platinum, crystal structure platinum sulfur ylide complex, mol structure platinum sulfur ylide complex, Organometallic and Organometalloidal Compounds: Group Viii – Co, Ni, Ru, Rh, Pd, Os, Ir, Pt and other aspects.Product Details of 5034-06-0
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