On September 15, 2021, Lu, Ronghua; Yang, Tilong; Chen, Xin; Fan, Wenzheng; Chen, Pinhong; Lin, Zhenyang; Liu, Guosheng published an article.Name: tert-Butyl trichloroacetimidate The title of the article was Enantioselective Copper-Catalyzed Radical Cyanation of Propargylic C-H Bonds: Easy Access to Chiral Allenyl Nitriles. And the article contained the following:
The first enantioselective copper-catalyzed cyanation of propargylic C-H bonds via radical relay was established using novel BoxOTMS ligands, providing an efficient and straightforward tool for the construction of structurally diverse chiral allenyl nitriles in good yields with excellent enantioselectivities. This reaction features high functional group tolerance and mild conditions. In addition, the chiral allene products can be readily converted to other chiral compounds via axis-to-center chirality transfer. The experimental process involved the reaction of tert-Butyl trichloroacetimidate(cas: 98946-18-0).Name: tert-Butyl trichloroacetimidate
The Article related to trimethylsilyl cyanide aralakyl alkyne copper catalyst enantioselective chemoselective cyanation, aryl allenyl nitrile preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Name: tert-Butyl trichloroacetimidate
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics