On January 21, 2013, Budovska, Mariana; Kutschy, Peter; Kozar, Tibor; Gondova, Tatana; Petrovaj, Jan published an article.Category: chlorides-buliding-blocks The title of the article was Synthesis of spiroindoline phytoalexin (S)-(-)-spirobrassinin and its unnatural (R)-(+)-enantiomer. And the article contained the following:
The stereoselective syntheses of the cruciferous indole phytoalexin (S)-(-)-spirobrassinin and its unnatural (R)-(+)-enantiomer were achieved by bromine-induced spirocyclization of (-)- and (+)-1-(8-phenylmenthoxycarbonyl)brassinin in the presence of water to give the corresponding spirobrasinol derivatives, followed by oxidation to the derivatives of spirobrassinin and finally removal of the chiral auxiliary. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Category: chlorides-buliding-blocks
The Article related to spirobrassinin stereoselective synthesis spirocyclization, Biomolecules and Their Synthetic Analogs: Others, Including Purines, Pyrimidine Nucleic Acid Bases, Flavins, Lignans and other aspects.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics