On April 15, 2022, Song, Heng; Shen, Yang; Zhou, Hu; Ding, Danli; Yang, Fu; Wang, Yemei; Xu, Chen; Cai, Xingwei published an article.Recommanded Product: 38939-88-7 The title of the article was Light-Promoted Low-Valent-Tungsten-Catalyzed Ambient Temperature Amination of Boronic Acids with Nitroaromatics. And the article contained the following:
A low-valent-tungsten-catalyzed reaction that enables the ambient temperature amination of boronic acids with nitroaroms. was disclosed. With readily available W(CO)6 as a precatalyst under external-photosensitizer-free conditions, nitroaroms. smoothly underwent C-N coupling reactions with their boronic acid partners, delivering structurally diverse secondary amines in good yields (>50 examples, yields up to 96%). This methodol. is both scalable and highly chemoselective and engages both aliphatic and aromatic boronic acid partners. The catalysis was initiated by the deoxygenation of nitroaroms. by a trans-[W(CO)4(PPh3)2] (trans-W, PPh3 = triphenylphosphine) complex, which formed in-situ via ligand replacement. The experimental process involved the reaction of 2-Chloro-4-methyl-1-nitrobenzene(cas: 38939-88-7).Recommanded Product: 38939-88-7
The Article related to nitroarene boronic acid tungsten catalyst chemoselective photochem amination, aryl amine preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Recommanded Product: 38939-88-7
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics