On April 7, 2017, Adhikari, Arijit A.; Suzuki, Tamie; Gilbert, Reesheda T.; Linaburg, Matthew R.; Chisholm, John D. published an article.Recommanded Product: 98946-18-0 The title of the article was Rearrangement of Benzylic Trichloroacetimidates to Benzylic Trichloroacetamides. And the article contained the following:
The rearrangement of allylic trichloroacetimidates is a well-known transformation, but the corresponding rearrangement of benzylic trichloroacetimidates has not been explored as a method for the synthesis of benzylic amines. Conditions that provide the trichloroacetamide product from a benzylic trichloroacetimidate in high yield have been developed. Methods were also investigated to transform the trichloroacetamide product directly into the corresponding amine, carbamate, and urea. A cationic mechanism for the rearrangement is implicated by the available data. The experimental process involved the reaction of tert-Butyl trichloroacetimidate(cas: 98946-18-0).Recommanded Product: 98946-18-0
The Article related to rearrangement benzylic trichloroacetimidate synthesis, benzylic trichloroacetamide preparation rearrangement benzyl trichloroacetimidate, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Recommanded Product: 98946-18-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics