Lundgren, Rylan J.; Stradiotto, Mark published an article in 2010, the title of the article was Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Tosylates with Hydrazine.Application In Synthesis of 4-Chloro-2-fluorotoluene And the article contains the following content:
The cross-coupling of aryl chlorides and tosylates with hydrazine in presence of cinnamylpalladium chloride dimer and 4-[2-(bis(1-adamantanyl)phosphinyl)phenyl]morpholine proceeds rapidly with excellent chemoselectivity under mild conditions. The experimental process involved the reaction of 4-Chloro-2-fluorotoluene(cas: 452-75-5).Application In Synthesis of 4-Chloro-2-fluorotoluene
The Article related to coupling aryl chloride tosylate hydrazine palladium adamantylphosphinylphenylmorpholine catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydroxylamines, Hydrazines, Triazenes, Azides, Azines, and Azo and Diazo Compounds and other aspects.Application In Synthesis of 4-Chloro-2-fluorotoluene
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics