On June 10, 2013, Watanabe, Yutaka; Uemura, Tsuyoshi; Yamauchi, Satoe; Tomita, Kousei; Saeki, Takafumi; Ishida, Ryousuke; Hayashi, Minoru published an article.Recommanded Product: 14602-86-9 The title of the article was Regioselective functionalization of unprotected myo-inositol by electrophilic substitution. And the article contained the following:
Unprotected myo-inositol was treated with various electrophiles, such as aroyl chlorides, tosyl chloride and tert-butyldiphenylsilyl chloride in a solution of LiCl/DMA or DMSO to afford regioselectively 1,3-di-O-substituted or racemic 1-O-substituted derivatives, e.g. I, depending on a quantity of reagents and reaction time. reaction with the solvents. α-Unbranched alkanoic acid anhydrides in LiCl/DMA in the presence of triethylamine were suitable for acylation of myo-inositol, in contrast to the fact that acylation using alkanoyl chlorides in aprotic polar solvents generally does not proceed well due to decomposition of the reagents by the. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Recommanded Product: 14602-86-9
The Article related to acylation inositol alkanoyl chloride regioselective electrophilic substitution cyclitol preparation, regioselective electrophilic substitution inositol aroyl chloride alkanoic acid anhydride and other aspects.Recommanded Product: 14602-86-9
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics