Sone, Toshihiko; Lu, Gang; Matsunaga, Shigeki; Shibasaki, Masakatsu published an article in 2009, the title of the article was Catalytic asymmetric synthesis of 2,2-disubstituted oxetanes from ketones by using a one-pot sequential addition of sulfur ylide.Computed Properties of 5034-06-0 And the article contains the following content:
Enantiopure 2-Me-2-R-substituted oxetanes (R = n-octyl, 9-decenyl, cyclohexyl, Ph, 4-ClC6H4, 4-FC6H4, PhCH2CH2, 2-naphthyl) were synthesized from the corresponding ketones RCOMe and dimethyloxosulfonium methylide via one-pot double methylene transfer catalyzed by a heterobimetallic La/Li complex. Chiral amplification in the second step was the key to obtain oxetanes in high enantiomeric excess. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Computed Properties of 5034-06-0
The Article related to oxetane disubstituted asym synthesis, ketone asym addition sulfur ylide heterobimetallic lanthanum lithium catalyst, oxirane kinetic resolution sulfur ylide addition lanthanum lithium catalyst and other aspects.Computed Properties of 5034-06-0
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