Pathak, Kriti team published research in Chemistry – A European Journal in 2022 | 12112-67-3

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Application In Synthesis of 12112-67-3

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Application In Synthesis of 12112-67-3.

Pathak, Kriti;Gayen, Sourav;Saha, Suvam;Nandi, Chandan;Mishra, Shivankan;Ghosh, Sundargopal research published 《 Coordination and Hydroboration of Ru(II)-Borate Complexes: Dihydridoborate vs. Bis(dihydridoborate)》, the research content is summarized as follows. Treatment of [Cp*RuCl2]2, 1, [(COD)IrCl]2, 2 or [(p-cymene)RuCl2]2, 3 (Cp* = η5-C5Me5, COD = 1,5-cyclooctadiene and p-cymene = η6–iPrC6H4Me) with heterocyclic borate ligands Na[(H3B)L], L1 and L2 (L1: L = amt, L2: L = mp; amt = 2-amino-5-mercapto-1,3,4-thiadiazole, mp = 2-mercaptopyridine) gave borate complexes having uncommon coordination. For example, complexes 1 and 2 on reaction with L1 and L2 afforded dihydridoborate species [LAM(μ-H)2BHL] 4–6 (4: LA = Cp*, M = Ru, L = amt; 5: LA = Cp*, M = Ru, L = mp; 6: LA = COD, M = Ir, L = mp). However, treatment of 3 with L2 yielded cis- and trans-bis(dihydridoborate) species, [Ru{(μ-H)2BH(mp)}2], cis-7 and trans-7. The isolation and structural characterization of fac- and mer-[Ru{(μ-H)2BH(mp)}{(μ-H)BH(mp)2}], 8 from the same reaction offered an insight into the behavior of these dihydridoborate species in solution Fascinatingly, despite having reduced natural charges on Ru centers both at cis-7 and trans-7, they underwent hydroboration reaction with alkynes that yielded both Markovnikov and anti-Markovnikov addition products, 10a–d.

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Application In Synthesis of 12112-67-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics