Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Lu, Ying-Bo;Chen, Chuan-Fu;Hu, Yi-Hu;Zhang, Xi-Chang;Fang, Qiang;Yang, Li-Yao;Xie, Lin-Jie;Wu, Jing;Li, Shijun research published 《 Self-Assembly of a Chiral Bis-phosphine Ligand Bearing Pyridyl Crown Ethers and Chiral Primary Ammoniums: Application to Catalytic Asymmetric Hydrogenation Reactions》, the research content is summarized as follows. A chiral bis-phosphine ligand bearing two pyridyl crown ethers was complexed with primary ammonium salts of different absolute configuration to form supramol. chiral catalysts, which were successfully applied in the Rh-catalyzed asym. hydrogenation of α-dehydroamino acid esters and Ir-catalyzed asym. hydrogenation of quinoxalines. By comparison with the non-assembled catalysts, the complexation between the chiral catalysts and primary ammoniums obviously improved enantioselectivities. Up to 11% enhancement in ee values in asym. hydrogenation of α-dehydroamino acid esters and 30% enhancement in ee values in asym. hydrogenation of quinoxalines were achieved.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics