Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Liu, Xi-Jia;Zhang, Wen-Yun;Zheng, Chao;You, Shu-Li research published 《 Iridium-Catalyzed Asymmetric Allylic Substitution of Methyl Azaarenes》, the research content is summarized as follows. Herein, an Ir-catalyzed asym. allylic substitution reaction of Me azaarenes was described. Azaarenes such as (benzo)thiazole, oxazole, benzoimidazole, pyridine, and (iso)quinoline were all tolerated. The corresponding chiral azaarene derivatives were obtained in good yields with high enantioselectivity (up to 96% yield and 99% ee). The utilization of the Knochel reagent TMPZnBr·LiBr warranted the in situ formation of benzylic nucleophiles without addnl. activating reagents. NMR studies suggested a two-fold function of the Knochel reagent in this reaction. The synthetic utility of this method was showcased by a concise enantioselective synthesis of an allosteric protein kinase modulator.
Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics