Computed Properties of C6H4Cl2O2SIn 2022 ,《Palladium-catalyzed cascade Heck-type thiocarbonylation for the synthesis of functionalized thioesters》 was published in Organic Chemistry Frontiers. The article was written by Xu, Ren-Rui; Wang, Wei; Qi, Xinxin; Wu, Xiao-Feng. The article contains the following contents:
A palladium-catalyzed cascade Heck-type cyclization and carbonylation reaction has been developed for the synthesis of functionalized thioesters. With arylsulfonyl chlorides as odorless and readily available sulfur sources, a variety of thioesters were obtained in moderate to good yields with good functional group compatibility. In this system, Mo(CO)6 acts as both a convenient CO surrogate and a suitable reductant. After reading the article, we found that the author used 4-Chlorobenzenesulfonyl chloride(cas: 98-60-2Computed Properties of C6H4Cl2O2S)
4-Chlorobenzenesulfonyl chloride(cas: 98-60-2) belongs to organochlorine compounds. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties.Computed Properties of C6H4Cl2O2S Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics