Duan, Shao-Bo; Gao, Xu-Jing; Zhang, Hong-Yu; Lu, Cong-Cong; Zhao, Jiquan; Han, Ya-Ping; Zhang, Yuecheng; Liang, Yong-Min published their research in Arabian Journal of Chemistry in 2021. The article was titled 《Palladium-catalyzed intramolecular tandem dearomatization of indoles for the synthesis of tetracyclic indolines》.Reference of (3-Fluorophenyl)boronic acid The article contains the following contents:
A highly diastereoselective, atom-economical, and palladium-catalyzed Heck protocol for the assembly of structurally diverse indoline scaffolds with vicinal tertiary as well as quaternary stereocenters is described, starting from readily available N-halobenzoyl o-haloaniline derivatives and phenylboronic acids. This cascade annulation reaction, which is scalable and conducts under an ambient atm., provides the valuable tetracyclic indoline derivatives in an efficient and straightforward way. The experimental process involved the reaction of (3-Fluorophenyl)boronic acid(cas: 768-35-4Reference of (3-Fluorophenyl)boronic acid)
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Reference of (3-Fluorophenyl)boronic acid
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