HPLC of Formula: 620-20-2On November 17, 2020 ,《Unsymmetrical Disulfides Synthesis via Cs2CO3-Catalyzed Three-Component Reaction in Water》 appeared in Advanced Synthesis & Catalysis. The author of the article were Wang, Dungai; Gao, Yuanji; Tong, Yunli; Xiong, Mingteng; Liang, Xiao; Zhu, Heping; Pan, Yuanjiang. The article conveys some information:
An unsym. disulfide synthesis by Cs2CO3-catalyzed three-component coupling reaction of thioacetates RSC(O)Me (R = 4-CH3OC6H4, CH2C6H5, oxolan-2-ylmethyl, etc.), sodium thiosulfate, and benzyl halide R1CH2Cl (R1 = C6H5, 4-BrC6H4, 1-naphthyl, etc.) in water has been described. The safe, stable, and non-toxic Na2S2O3 was invoked as the sulfur-source, successfully avoiding the odor generation in the process of S-S bond formation. A wide range of substrate suitability and appropriate functional group tolerance were observed for the transformation. Notably, the approach reported here was compatible with various biomols. including glucose, coumarin, and quinolinone. In addition to this study using 3-Chlorobenzylchloride, there are many other studies that have used 3-Chlorobenzylchloride(cas: 620-20-2HPLC of Formula: 620-20-2) was used in this study.
3-Chlorobenzylchloride(cas: 620-20-2) has been used in the reaction of 3-methoxybenzyl chloride and ethyl 4-bromobenzoate in pure water, using zinc dust and a Pd catalyst.HPLC of Formula: 620-20-2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics