《Visible-light Driven Hydrolysis of Benzyl Halides with Water for Preparation of Benzyl Alcohols》 was written by Xu, Jianbin; Liu, Na; Zou, Lingling; Cheng, Feixiang; Shen, Xianfu; Liu, Teng; Lv, Haiping; Khan, Ruhima; Fan, Baomin. Application of 622-95-7This research focused onwater benzyl halide rhodamine B catalyst photochem hydrolysis; benzyl alc preparation. The article conveys some information:
Visible-light-mediated hydrolysis of benzyl halides were achieved that was efficiently catalyzed by metal-free catalyst rhodamine B. Benzyl bromides and chlorides were smoothly reacted with water to prepare a series of benzyl alc. compounds in good yields. After reading the article, we found that the author used 1-(Bromomethyl)-4-chlorobenzene(cas: 622-95-7Application of 622-95-7)
1-(Bromomethyl)-4-chlorobenzene(cas: 622-95-7) undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid.Application of 622-95-7 It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics