Simpson, Harold N.; Hancock, C. Kinney; Meyers, Edward A. published the artcile< The correlation of the electronic spectra, acidities, and polarographic oxidation half-wave potentials of 4-substituted 2-chlorophenols with substituent constants>, Related Products of 3964-57-6, the main research area is .
The electronic spectra, pKA values, and polarographic oxidation half-wave potentials of a series of 4-substituted 2-chlorophenols (I) have been measured. Correlations of these data have been made and compared with correlations previously reported for a series of 4-substituted 2-nitrophenols (II) and a series of 5-substituted 2-nitrophenols (III). For all three of these series, there are excellent correlations between pKA and σ, with the ρ value of -2.22 for I agreeing closely with that of -2.16 for II but being much more positive than that of -3.01 for III. As with II and III, there is a good correlation between νB and νA, but the relationship between Δν and pKA is unsatisfactory. Excellent correlations exist between E1/2 and σ and between E1/2 and pKA. These and other relationships are discussed.
Journal of Organic Chemistry published new progress about 3964-57-6. 3964-57-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H7ClO3, Related Products of 3964-57-6.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics