Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)[(蟺-dicyclopentadiene)platinum] disulfide was written by Pasynskii, A. A.;Semenova, N. I.;Torubaev, Yu. V.;Lysenko, K. A.. And the article was included in Zhurnal Neorganicheskoi Khimii in 2001.Recommanded Product: 12083-92-0 This article mentions the following:
Transmetalation of (渭3-S)2Fe3(CO)9 with C10H12PtCl2 (C10H12 = dicyclopentadiene) in THF gave 55% title cluster C10H12Pt(渭3-S)2Fe2(CO)6, the structure of which was determined by x-ray crystallog. The Pt atom is 蟺-coordinated with double bonds of the dicyclopentadiene mol. and with 2 渭3-bridging S atoms and is in a square planar environment. The Fe(CO)3 moieties show an Fe-Fe bond length of 2.515 脜. One of the Fe atoms forms an Fe-Pt bond of 3.03 脜 length with the Pt atom, and tilts the planarity of the Pt atom ligand environment toward itself. The role of the steric effects of interligand repulsion on Fe-Pt interaction is discussed. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Recommanded Product: 12083-92-0).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Recommanded Product: 12083-92-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics