Catalyst-free water-mediated N-Boc deprotection was written by Wang, Gan;Li, Chunju;Li, Jian;Jia, Xueshun. And the article was included in Tetrahedron Letters in 2009.Category: chlorides-buliding-blocks This article mentions the following:
A catalyst-free water-mediated N-Boc deprotection of N-Boc amines is reported. In the absence of any addnl. reagents, the free amines were formed from a variety of aromatic and aliphatic N-Boc amines as well as from some N-Boc amino acid derivatives In the experiment, the researchers used many compounds, for example, tert-Butyl (4-chlorophenyl)carbamate (cas: 18437-66-6Category: chlorides-buliding-blocks).
tert-Butyl (4-chlorophenyl)carbamate (cas: 18437-66-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics