Iron-Platinum interaction in (hexacarbonyldiiron)-[(π-diene)platinum] dichalcogenide clusters was written by Pasynskii, A. A.;Semenova, N. I.;Torubaev, Yu. V.;Lysenko, K. A.. And the article was included in Zhurnal Neorganicheskoi Khimii in 2003.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:
Trinuclear diiron-platinum cluster [(diene)Pt(μ3-Se)2Fe2(CO)6] (2, diene = dicyclopentadiene) was prepared by transmetalation of [(μ3-Se)2Fe3(CO)9] by [(diene)PtCl2]. Crystal structure of 2 was determined by single-crystal x-ray crystallog. Platinum atom in 2 has a square-planar coordination geometry and is η2-bound to double bonds of the dicyclopentadiene ligand and coordinated by μ3-Se atoms. The Fe(CO)3 fragments are bound by two selenium bridges and by Fe-Fe bond (2.545 Å). Besides that, one of the Fe atoms has close contact with platinum (Fe-Pt 3.169 Å), declining the Pt coordination plane from the mirror plane of the two Fe(CO)3 fragments. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)
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Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics