Air-stable nickel(II) borohydrides as prohydrides: Reactions with halocarbons and aerial carbon dioxide was written by Mani, Kalaikodikumaran;Pal, Parameswar;Anandababu, Karunanithi;Raje, Sakthi;Angamuthu, Raja. And the article was included in Inorganica Chimica Acta in 2021.Application In Synthesis of (Chloromethanetriyl)tribenzene This article mentions the following:
Non-noble metal hydrides are highly attractive reagents owing to their involvement in the reactions of environmental and industrial interest. However, they are often cumbersome to isolate as a shelf-stable reagent. Herein, the authors have described the synthesis of non-noble metal hydrides by simple manual grinding of Ni(II)-chelates and NaBH4 in open air at room temperature without using organic solvents. Two Ni(II) complexes of tetradentate N4 ligands, (LNHCy = N,N’-bis(pyrid-2-ylmethyl)cyclohexanediamine) [(LNHCy)Ni(MeCN)(H2O)](ClO4)2 and [(tren)Ni(MeCN)2](BPh4)2, were synthesized and their solid-state structures were confirmed by single crystal x-ray diffraction studies. Both the Ni complexes were manually ground with Na borohydride in open air to produce corresponding Ni(II)-borohydrides that were characterized using FTIR spectroscopy and powder x-ray diffraction techniques. Further, the borohydrides (prohydrides) activate the C-X bond in benzyl bromide, CDCl3, trityl chloride and iodobenzene to yield toluene, CHDCl2, triphenylmethane and benzene; the borohydrides reacted with trityl cation and air in MeCN solution to yield triphenylmethane and carbonate. In the experiment, the researchers used many compounds, for example, (Chloromethanetriyl)tribenzene (cas: 76-83-5Application In Synthesis of (Chloromethanetriyl)tribenzene).
(Chloromethanetriyl)tribenzene (cas: 76-83-5) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Application In Synthesis of (Chloromethanetriyl)tribenzene
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics