Kinetic and mechanistic approach of N-chlorosaccharin oxidation of some non vicinal polyhydroxy alcohols was written by Kaur, Raman Deep;Arora, Monika;Gujral, Harjeet;Kaur, Gurpreet;Nayak, S. N.;Singh, S. K.. And the article was included in International Journal of ChemTech Research in 2010.Electric Literature of C7H4ClNO3S This article mentions the following:
The kinetics of oxidation of propane-1,3-diol and butane-1,4-diol by N-chlorosaccharin was carried out in aqueous acetic acid medium. The reactions exhibit first order dependence in oxidant and the Michaelis-Menten’s kinetics in substrate. Increase in the concentration of added perchloric acid increases the rate of oxidation Addition of the reaction product, saccharin, exhibits retarding effect. Decrease in dielec. constant of the medium decreased the rate constant Various activation parameters have been evaluated. Mechanism proposed and the derived rate law is in agreement with the observed kinetics. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Electric Literature of C7H4ClNO3S).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of C7H4ClNO3S
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics