Aerobic Oxidation of Thiols and In Situ Generated Thiols to Symmetrical Disulfides (Disulfanes) Catalyzed by Na2S4O6 was written by Abbasi, Mohammad;Nowrouzi, Najmeh;Mousavi, Saadat. And the article was included in ChemistrySelect in 2019.Recommanded Product: 1-(Chloromethyl)-3-methylbenzene This article mentions the following:
A simple and efficient procedure for aerobic oxidation of thiols RSH (R = cyclopentyl, Bu, (4-methylphenyl)methyl, etc.) into sym. disulfides RSSR using Na2S4O6 as catalyst in situ generated by reacting Na2S2O3 with I2 in poly ethylene glycol (PEG-200) has been introduced. Using this catalyst system, a convenient protocol for one-pot achievement of sym. disulfides R1SSR1 (R1 = cyclohexyl, (2-methylphenyl)methyl, prop-2-en-1-yl, etc.) via aerobic oxidation of thiols R1S in situ generated by reacting alkyl halides R1X (X = I, Cl, Br) with thiourea is introduced. In the experiment, the researchers used many compounds, for example, 1-(Chloromethyl)-3-methylbenzene (cas: 620-19-9Recommanded Product: 1-(Chloromethyl)-3-methylbenzene).
1-(Chloromethyl)-3-methylbenzene (cas: 620-19-9) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 1-(Chloromethyl)-3-methylbenzene
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics