Biocatalytic Enantioselective Oxidative C-C Coupling by Aerobic C-H Activation was written by Schrittwieser, Joerg H.;Resch, Verena;Sattler, Johann H.;Lienhart, Wolf-Dieter;Durchschein, Katharina;Winkler, Andreas;Gruber, Karl;Macheroux, Peter;Kroutil, Wolfgang. And the article was included in Angewandte Chemie, International Edition in 2011.Computed Properties of C9H9ClO2 This article mentions the following:
The berberine bridge enzyme (BBE) was employed for the first preparative oxidative biocatalytic C-C coupling that leads to a new intramol. bond. This unique transformation requires O2 as sole stoichiometric oxidant and gives access to novel optically pure (S)-berbine and (R)-1-benzyl-1,2,3,4-tetrahydroisoquinoline alkaloid derivatives by kinetic resolution In the experiment, the researchers used many compounds, for example, 2-(3-Methoxyphenyl)acetyl chloride (cas: 6834-42-0Computed Properties of C9H9ClO2).
2-(3-Methoxyphenyl)acetyl chloride (cas: 6834-42-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Computed Properties of C9H9ClO2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics