Jaiswal, Kuldeep et al. published their research in Journal of the American Chemical Society in 2021 | CAS: 76-83-5

(Chloromethanetriyl)tribenzene (cas: 76-83-5) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: C19H15Cl

Carborane Stabilized “19-Electron” Molybdenum Metalloradical was written by Jaiswal, Kuldeep;Malik, Naveen;Tumanskii, Boris;Menard, Gabriel;Dobrovetsky, Roman. And the article was included in Journal of the American Chemical Society in 2021.Formula: C19H15Cl This article mentions the following:

Molybdenum 19-e paramagnetic complexes stabilized by carboranylphosphine 1,2-C2B10H11PPh2 (CbPPh2) were prepared by photolysis of half-sandwich Mo-Mo dimer [Cp2Mo2(CO)6] in the presence of CbPPh2. Paramagnetic metal complexes gained a lot of attention due to their participation in a number of important chem. reactions. In most cases, these complexes are dominated by 17-e metalloradicals that are associatively activated with highly reactive paramagnetic 19-e species. Molybdenum paramagnetic complexes are among the most investigated ones. While some examples of persistent 17-e Mo-centered radicals have been reported, in contrast, 19-e Mo-centered radicals are illusive species and as such could rarely be detected. In this work, the photodissociation of the [Cp(CO)3Mo]2 dimer (1) in the presence of phosphines was revisited. As a result, the first persistent, formally 19-e Mo radical with significant electron d. on the Mo center (22%), Cp(CO)3Mo•PPh2(o-C2B10H11) (5b), was generated and characterized by EPR spectroscopy and MS as well as studied by DFT calculations The stabilization of 5b was likely achieved due to a unique electron-withdrawing effect of the o-carboranyl substituent at the phosphorus center. In the experiment, the researchers used many compounds, for example, (Chloromethanetriyl)tribenzene (cas: 76-83-5Formula: C19H15Cl).

(Chloromethanetriyl)tribenzene (cas: 76-83-5) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: C19H15Cl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics