Mechanism of radical chlorination of hydrocarbons with N-halosulfonamides. Effect of structural factors on the reaction selectivity was written by Dneprovskii, A. S.;Eliseenkov, E. V.;Osmonov, T. A.. And the article was included in Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii) in 1998.Recommanded Product: 14070-51-0 This article mentions the following:
Radical chlorination of alkanes and their derivatives with N-halosulfonamides was studied by the method of competing reactions under conditions where H is abstracted only by sulfonylaminyl radical. The selectivity of reactions with N-halosulfonamides is intermediate between radical chlorination and bromination with mol. halogens. Radicals with captodative properties exhibit the highest selectivity. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Recommanded Product: 14070-51-0).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Recommanded Product: 14070-51-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics