Zaki, Ahmad et al. published their research in Journal of the Chemical Society in 1932 | CAS: 5335-05-7

Chloromethyl benzoate (cas: 5335-05-7) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Application In Synthesis of Chloromethyl benzoate

Benzoic esters and electronic affinities of radicals. III was written by Zaki, Ahmad. And the article was included in Journal of the Chemical Society in 1932.Application In Synthesis of Chloromethyl benzoate This article mentions the following:

The glycol dibenzoates supply evidence for the order Cl > O > H with regard to m-nitration induced by substitution in a saturated chain; the following percentages of m-NO2 compound were obtained for n = 1, 2 and 3: BzO(CH2)n-OBz 80.8, 74.8, 75.8; BzO(CH2)nH 72.6, 69.6, 71.8; BzO(CH2)nCl 81.9, 75.8, 77.7. Nitration of cyclohexyl benzoates gave the following percentages of m-NO2 compound: cyclohexyl 67; 2-Me derivative 65.4; 3-Me derivative 67.2; 4-Me derivative 67.3; these figures confirm the hypothesis that the repulsion of electrons is increased by increasing C substitution. Since the values are appreciably higher than those for hexyl benzoate (63.7%), this can only be due to the closure of the ring; ring closure alone, however, which produced but a small effect (3%), can be responsible for only a small fraction of the difference (20%) observed in the benzylamine bases. The percentages of m-nitration of the 3 nitrobenzyl benzoates were: o-76, m- 73, p- 75; these show that all the O2NC6H4CH2 radicals are less directive than Me. Benzodiethylamide gives an average of 29.5% m-nitration; benzoylpiperidine 31%; benzamide 69%. m-Nitration is therefore considerably lowered by the substitution of the H atoms of the NH2 group. Aryl benzoates are also discussed. In the experiment, the researchers used many compounds, for example, Chloromethyl benzoate (cas: 5335-05-7Application In Synthesis of Chloromethyl benzoate).

Chloromethyl benzoate (cas: 5335-05-7) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Application In Synthesis of Chloromethyl benzoate

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics